Difference between revisions of "Oxford ICP Etcher - Process Control Data"

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(added "sample prep" section - still needs solution detials added)
(added chamber wet clean)
 
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__TOC__
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==Data - InP Ridge Etch (Oxford ICP Etcher)==
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==Process Control Data - InP Ridge Etch (Oxford ICP Etcher)==
 
[[PECVD1-(PlasmaTherm 790)|PECVD SiO2]] hardmask, patterned on [[Stepper 1 (GCA 6300)|Stepper #2 (AutoStep 200)]] & [[ICP Etch 1 (Panasonic E626I)|Panasonic ICP #1]]
 
[[PECVD1-(PlasmaTherm 790)|PECVD SiO2]] hardmask, patterned on [[Stepper 1 (GCA 6300)|Stepper #2 (AutoStep 200)]] & [[ICP Etch 1 (Panasonic E626I)|Panasonic ICP #1]]
 
{| class="wikitable"
  
{| class="wikitable"
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<u>Seasoning</u>: 10min “Std Clean - O2/SF6 Chamber Clean 20C (Edit Time)”, then load 2” “dummy” unpatterned InP wafer pieces on Si carrier (rough side up) and run 5min of “Std InP Ridge Etch - Cl2/CH4/H2 60C”
 
<u>Seasoning</u>: 10min “Std Clean - O2/SF6 Chamber Clean 20C (Edit Time)”, then load 2” “dummy” unpatterned InP wafer pieces on Si carrier (rough side up) and run 5min of “Std InP Ridge Etch - Cl2/CH4/H2 60C”
   
−
<u>Sample Prep</u>: Prior to dry etching, the sample is submerged in NH4OH:DI solution (XYZ:XYZ) for XYZ min, then DI rinsed and N2 dried.
+
<u>Sample Prep</u>: Prior to dry etching, the sample is submerged in NH4OH : DI =  1:10 (3mL:30mL) for 1 min, then DI rinsed and N2 dried.
 
|-
  
|-
 
!'''Date'''
  
!'''Date'''
Line 15: Line 16:
 
!'''Comments'''
  
!'''Comments'''
 
!'''SEM Images'''
  
!'''SEM Images'''
  +
|-
  +
|01/11/23
  +
|ND_60c_011123
  +
|296
  +
|12.7
  +
|
  +
|[https://wiki.nanotech.ucsb.edu/w/images/3/32/30D_oxford_011123_002.jpg <nowiki>[30D]</nowiki>][https://wiki.nanotech.ucsb.edu/w/images/4/4a/Cs_oxford_011123_002.jpg <nowiki>[CS]</nowiki>]
  +
|-
  +
|12/21/22
  +
|Tony Bosch
  +
| colspan="4" |''Chamber wet-cleaned, significant buildup observed & cleaned up.''
  +
|-
  +
|12/14/22
  +
|ND_60c_120922
  +
|248
  +
|9.1
  +
|Very low etch rate and selectivity
  +
|[https://wiki.nanotech.ucsb.edu/w/images/8/8c/30D_oxford_121422_002.jpg <nowiki>[30D]</nowiki>][https://wiki.nanotech.ucsb.edu/w/images/3/33/CS_oxford_121422_002.jpg <nowiki>[CS]</nowiki>]
  +
|-
  +
|11/18/22
  +
|ND_60c_111822
  +
|324
  +
|15.2
  +
|
  +
|[https://wiki.nanotech.ucsb.edu/w/images/3/3d/30D_oxford_111822_002.jpg <nowiki>[30D]</nowiki>][https://wiki.nanotech.ucsb.edu/w/images/2/2f/CS_oxford_111822_002.jpg <nowiki>[CS]</nowiki>]
  +
|-
  +
|11/11/22
  +
|ND_60c_111122
  +
|312
  +
|11.4
  +
|
  +
|[https://wiki.nanotech.ucsb.edu/w/images/b/b6/30D_oxford_111122_002.jpg <nowiki>[30D]</nowiki>] [https://wiki.nanotech.ucsb.edu/w/images/9/90/CS_oxford_111122_002.jpg <nowiki>[CS]</nowiki>]
  +
|-
  +
|10/24/22
  +
|ND_60c_102422
  +
|286
  +
|13.4
  +
|
  +
|[https://wiki.nanotech.ucsb.edu/w/images/b/b1/30D_oxford_102422_002.jpg <nowiki>[30D]</nowiki>][https://wiki.nanotech.ucsb.edu/w/images/a/a7/CS_oxford_102422_002.jpg <nowiki>[CS]</nowiki>]
  +
|-
  +
|10/14/22
  +
|ND_60c_101422
  +
|344
  +
|14.8
  +
|
  +
|[https://wiki.nanotech.ucsb.edu/w/images/d/d3/30D_oxford_101422_002.jpg <nowiki>[30D]</nowiki>] [https://wiki.nanotech.ucsb.edu/w/images/8/83/CS_oxford_101422_002.jpg <nowiki>[CS]</nowiki>]
  +
|-
  +
|10/3/22
  +
|ND_60c_100322
  +
|322
  +
|12.7
  +
|
  +
|[https://wiki.nanotech.ucsb.edu/w/images/e/ef/30D_10302022_oxford_002.jpg <nowiki>[30D]</nowiki>] [https://wiki.nanotech.ucsb.edu/w/images/c/c3/CS_10302022_oxford_002.jpg <nowiki>[CS]</nowiki>]
  +
|-
  +
|9/30/22
  +
|ND_60c_093022
  +
|312
  +
|16.9
  +
|High etch rate and selectivity
  +
|[https://wiki.nanotech.ucsb.edu/w/images/d/dd/30D_oxford_09302022_002.jpg <nowiki>[30D]</nowiki>] [https://wiki.nanotech.ucsb.edu/w/images/2/23/CS_oxford_093022_004_%28copy%29.jpg <nowiki>[CS]</nowiki>]
  +
|-
  +
|9/6/22
  +
|ND_60c_090622
  +
|246
  +
|7.5
  +
|Very low etch rate and selectivity
  +
|[https://wiki.nanotech.ucsb.edu/w/images/f/fb/30D_oxford_09062022_002.jpg <nowiki>[30D]</nowiki>] [https://wiki.nanotech.ucsb.edu/w/images/e/e3/CS_oxford_09062022_002.jpg <nowiki>[CS]</nowiki>]
  +
|-
  +
|9/1/22
  +
|ND_60c_090122
  +
|268
  +
|9.4
  +
|Low Etch rate/selectivity, could be due to recent Cl2 clean
  +
|[https://wiki.nanotech.ucsb.edu/w/images/5/5f/30D_oxford_090122_002.jpg <nowiki>[45D]</nowiki>] [https://wiki.nanotech.ucsb.edu/w/images/5/5c/CS_oxford_090122_002.jpg <nowiki>[CS]</nowiki>]
  +
|-
  +
|8/1/22
  +
|ND_60c_080122
  +
|298
  +
|9.9
  +
|
  +
|[https://wiki.nanotech.ucsb.edu/w/images/2/2e/CS_002.jpg <nowiki>[CS]</nowiki>] [https://wiki.nanotech.ucsb.edu/w/images/8/82/45D_001.jpg <nowiki>[45D]</nowiki>]
  +
|-
  +
|7/1/22
  +
|ND_60c_070122
  +
|294
  +
|11.9
  +
|Did not dip in NH4OH
  +
|[https://wiki.nanotech.ucsb.edu/w/images/6/65/45D_001_8-1-22.jpg <nowiki>[45D]</nowiki>] [https://wiki.nanotech.ucsb.edu/w/images/d/d7/InP_07012022_CS_001_copy.jpg <nowiki>[CS]</nowiki>]
  +
|-
  +
|5/19/22
  +
|DJ_60c_007
  +
|326
  +
|TBA
  +
|After chamber vented, cleaned (wet + dry). Forgot NH<sub>4</sub>OH wet-etch before dry etch. ER and profile look nominal.
  +
|[[Media:Oxford InP 60C 45DEG02.jpg|[45°1]]],[[Media:Oxford InP 60C 45DEG05.jpg|[45°2]]] [[Media:Oxford InP 60C XS05.jpg|[XS]]]
 
|-
  
|-
 
|5/11/22
  
|5/11/22
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|9.76
  
|9.76
 
|
  
|
−
|[https://wiki.nanotech.ucsb.edu/w/images/2/25/Oxford_60c_10_45D_003.jpg <nowiki>[1]</nowiki>] [https://wiki.nanotech.ucsb.edu/w/images/a/aa/Oxford_60c_10_CS_008.jpg <nowiki>[2]</nowiki>]
 +
|[https://wiki.nanotech.ucsb.edu/w/images/2/25/Oxford_60c_10_45D_003.jpg <nowiki>[45°]</nowiki>] [https://wiki.nanotech.ucsb.edu/w/images/a/aa/Oxford_60c_10_CS_008.jpg <nowiki>[XS]</nowiki>]
 
|-
  
|-
 
|5/4/22
  
|5/4/22
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|10.5
  
|10.5
 
|
  
|
−
|[https://wiki.nanotech.ucsb.edu/w/images/e/e8/InP_Oxford_60c_09_45D_005.jpg <nowiki>[1]</nowiki>] [https://wiki.nanotech.ucsb.edu/w/images/3/3a/InP_Oxford_60c_09_CS_005.jpg <nowiki>[2]</nowiki>]
 +
|[https://wiki.nanotech.ucsb.edu/w/images/e/e8/InP_Oxford_60c_09_45D_005.jpg <nowiki>[45°]</nowiki>] [https://wiki.nanotech.ucsb.edu/w/images/3/3a/InP_Oxford_60c_09_CS_005.jpg <nowiki>[XS]</nowiki>]
 
|-
  
|-
 
|4/27/22
  
|4/27/22
Line 35: Line 131:
 
|9.2
  
|9.2
 
|directly after chamber clean. Identical results to before chamber clean. Chamber appeared clean when opened.
  
|directly after chamber clean. Identical results to before chamber clean. Chamber appeared clean when opened.
−
|[https://wiki.nanotech.ucsb.edu/w/images/b/b4/Oxford_60c_08_45D_003.jpg <nowiki>[1]</nowiki>] [https://wiki.nanotech.ucsb.edu/w/images/8/8d/Oxford_60c_08_CS_009.jpg <nowiki>[2]</nowiki>]
 +
|[https://wiki.nanotech.ucsb.edu/w/images/b/b4/Oxford_60c_08_45D_003.jpg <nowiki>[45°]</nowiki>] [https://wiki.nanotech.ucsb.edu/w/images/8/8d/Oxford_60c_08_CS_009.jpg <nowiki>[XS]</nowiki>]
 
|-
  
|-
 
|4/26/22
  
|4/26/22
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|9.93
  
|9.93
 
|day before chamber clean
  
|day before chamber clean
−
|[https://wiki.nanotech.ucsb.edu/w/images/6/66/Oxford_60c_07_45D_002.jpg <nowiki>[1]</nowiki>] [https://wiki.nanotech.ucsb.edu/w/images/2/25/Oxford_60c_07_CS_001.jpg <nowiki>[2]</nowiki>]
 +
|[https://wiki.nanotech.ucsb.edu/w/images/6/66/Oxford_60c_07_45D_002.jpg <nowiki>[45°]</nowiki>] [https://wiki.nanotech.ucsb.edu/w/images/2/25/Oxford_60c_07_CS_001.jpg <nowiki>[XS]</nowiki>]
 
|-
  
|-
 
|4/19/22
  
|4/19/22
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|9.53
  
|9.53
 
|Chamber opened and brown gunk observed in chamber right after the etch was done. Etch rate unaffected.
  
|Chamber opened and brown gunk observed in chamber right after the etch was done. Etch rate unaffected.
−
|[https://wiki.nanotech.ucsb.edu/w/images/0/03/Oxford_60c_06_45D_002.jpg <nowiki>[1]</nowiki>] [https://wiki.nanotech.ucsb.edu/w/images/7/7d/Oxford_60c_06_CS_005.jpg <nowiki>[2]</nowiki>]
 +
|[https://wiki.nanotech.ucsb.edu/w/images/0/03/Oxford_60c_06_45D_002.jpg <nowiki>[45°]</nowiki>] [https://wiki.nanotech.ucsb.edu/w/images/7/7d/Oxford_60c_06_CS_005.jpg <nowiki>[XS]</nowiki>]
 
|-
  
|-
 
|4/13/22
  
|4/13/22
Line 56: Line 152:
 
|11.51
  
|11.51
 
|New mask pattern with long lines to cleave through.
  
|New mask pattern with long lines to cleave through.
−
|[https://wiki.nanotech.ucsb.edu/w/images/1/12/Oxford_60c_05_45D_004.jpg <nowiki>[1]</nowiki>] [https://wiki.nanotech.ucsb.edu/w/images/5/56/Oxford_60c_05_CS_002.jpg <nowiki>[2]</nowiki>]
 +
|[https://wiki.nanotech.ucsb.edu/w/images/1/12/Oxford_60c_05_45D_004.jpg <nowiki>[45°]</nowiki>] [https://wiki.nanotech.ucsb.edu/w/images/5/56/Oxford_60c_05_CS_002.jpg <nowiki>[XS]</nowiki>]
 
|-
  
|-
 
!
  
!
Line 71: Line 167:
 
|*etched for 3min*
  
|*etched for 3min*
 
~30-40% SiO<sub>2</sub> masking (NingC's pattern)
  
~30-40% SiO<sub>2</sub> masking (NingC's pattern)
−
|[https://wiki.nanotech.ucsb.edu/w/images/8/8a/Oxford_60c_04_45D_001.jpg <nowiki>[1]</nowiki>][https://wiki.nanotech.ucsb.edu/w/images/0/0a/Oxford_60c_04_CS_004.jpg <nowiki>[2]</nowiki>]
 +
|[https://wiki.nanotech.ucsb.edu/w/images/8/8a/Oxford_60c_04_45D_001.jpg <nowiki>[45°]</nowiki>] [https://wiki.nanotech.ucsb.edu/w/images/0/0a/Oxford_60c_04_CS_004.jpg <nowiki>[XS]</nowiki>]
 
|-
  
|-
 
|1/26/22
  
|1/26/22
Line 78: Line 174:
 
|12.9
  
|12.9
 
|~30-40% SiO<sub>2</sub> masking (NingC's pattern)
  
|~30-40% SiO<sub>2</sub> masking (NingC's pattern)
−
|[https://wiki.nanotech.ucsb.edu/w/images/e/ef/Oxford_Cal_01_26_22_003New_45d_001.jpg <nowiki>[1]</nowiki>] [https://wiki.nanotech.ucsb.edu/w/images/4/40/Oxford_Cal_01_26_22_031New_CS_001.jpg <nowiki>[2]</nowiki>]
 +
|[https://wiki.nanotech.ucsb.edu/w/images/e/ef/Oxford_Cal_01_26_22_003New_45d_001.jpg <nowiki>[45°]</nowiki>] [https://wiki.nanotech.ucsb.edu/w/images/4/40/Oxford_Cal_01_26_22_031New_CS_001.jpg <nowiki>[XS]</nowiki>]
 
|}
  
|}
   
  +
==Sample Size Effect on Etch Rate (Oxford ICP Etcher)==
−
===Dependence on Sample Size===
  
−
We have found that the size of the InP piece loaded (no adhesive, onto Silicon carrier wafer) affects the etch rate, but does not affect the etch profile - ie. etches are still smooth and vertical, but rate varies with sample area.
 +
We have found that the size of the InP piece loaded (no adhesive, onto Silicon carrier wafer) affects the etch rate, but does not affect the etch profile - ie. '''etches are still smooth and vertical, but etch rate varies with sample area.'''
 
{| class="wikitable"
  
{| class="wikitable"
 
| colspan="8" |'''InP Ridge Etch''': 60°C, 3mT, 800W/65W, Cl2=18, H2=15, CH4=10sccm, time=5min05sec (305sec)
  
| colspan="8" |'''InP Ridge Etch''': 60°C, 3mT, 800W/65W, Cl2=18, H2=15, CH4=10sccm, time=5min05sec (305sec)

Latest revision as of 15:38, 12 January 2023

Process Control Data - InP Ridge Etch (Oxford ICP Etcher)

PECVD SiO2 hardmask, patterned on Stepper #2 (AutoStep 200) & Panasonic ICP #1

InP Ridge Etch: 60°C, 3mT, 800W/65W, Cl2=18, H2=15, CH4=10sccm, time=5min00sec (300sec)

Sample Size: 2” unpatterned InP wafer “dummy” pieces, surrounding 1x1cm patterned sample, ~30-40% SiO2 masking (NingC's pattern). Silicon carrier, no adhesive.

Seasoning: 10min “Std Clean - O2/SF6 Chamber Clean 20C (Edit Time)”, then load 2” “dummy” unpatterned InP wafer pieces on Si carrier (rough side up) and run 5min of “Std InP Ridge Etch - Cl2/CH4/H2 60C”

Sample Prep: Prior to dry etching, the sample is submerged in NH4OH : DI =  1:10 (3mL:30mL) for 1 min, then DI rinsed and N2 dried.

Date Sample# Etch Rate (nm/min) Etch Selectivity (InP/SiO2) Comments SEM Images
01/11/23 ND_60c_011123 296 12.7 [30D][CS]
12/21/22 Tony Bosch Chamber wet-cleaned, significant buildup observed & cleaned up.
12/14/22 ND_60c_120922 248 9.1 Very low etch rate and selectivity [30D][CS]
11/18/22 ND_60c_111822 324 15.2 [30D][CS]
11/11/22 ND_60c_111122 312 11.4 [30D] [CS]
10/24/22 ND_60c_102422 286 13.4 [30D][CS]
10/14/22 ND_60c_101422 344 14.8 [30D] [CS]
10/3/22 ND_60c_100322 322 12.7 [30D] [CS]
9/30/22 ND_60c_093022 312 16.9 High etch rate and selectivity [30D] [CS]
9/6/22 ND_60c_090622 246 7.5 Very low etch rate and selectivity [30D] [CS]
9/1/22 ND_60c_090122 268 9.4 Low Etch rate/selectivity, could be due to recent Cl2 clean [45D] [CS]
8/1/22 ND_60c_080122 298 9.9 [CS] [45D]
7/1/22 ND_60c_070122 294 11.9 Did not dip in NH4OH [45D] [CS]
5/19/22 DJ_60c_007 326 TBA After chamber vented, cleaned (wet + dry). Forgot NH4OH wet-etch before dry etch. ER and profile look nominal. [45°1],[45°2] [XS]
5/11/22 NP_60c_010 322 9.76 [45°] [XS]
5/4/22 NP_60c_009 318 10.5 [45°] [XS]
4/27/22 NP_60c_008 320 9.2 directly after chamber clean. Identical results to before chamber clean. Chamber appeared clean when opened. [45°] [XS]
4/26/22 NP_60c_007 312 9.93 day before chamber clean [45°] [XS]
4/19/22 NP_60c_006 330 9.53 Chamber opened and brown gunk observed in chamber right after the etch was done. Etch rate unaffected. [45°] [XS]
4/13/22 NP_60c_005 320 11.51 New mask pattern with long lines to cleave through. [45°] [XS]
↑ Changed mask pattern going forward (~50% open area), apparent etch rate changes due to measuring different features.
3/30/22 NP_60c_004 427 11.17 *etched for 3min*

~30-40% SiO2 masking (NingC's pattern)

[45°] [XS]
1/26/22 NP_1_26_003 452 12.9 ~30-40% SiO2 masking (NingC's pattern) [45°] [XS]

Sample Size Effect on Etch Rate (Oxford ICP Etcher)

We have found that the size of the InP piece loaded (no adhesive, onto Silicon carrier wafer) affects the etch rate, but does not affect the etch profile - ie. etches are still smooth and vertical, but etch rate varies with sample area.

InP Ridge Etch: 60°C, 3mT, 800W/65W, Cl2=18, H2=15, CH4=10sccm, time=5min05sec (305sec)

Silicon carrier, no adhesive.

Date Sample# Sample Size (dimensions, mm) Sample Size (area, mm2) Etch Rate (nm/min) Etch Selectivity (InP/SiO2) Comments SEM Images
1/11/22 DJ_InPRidge 4.5 x 2.5 11.25 602 64.6nm left ~50% SiO2 masking (GCA Calibration pattern) [1]
1/12/22 DJ_InPRidge 4.5 x 3 13.5 563 76.4nm left ~50% SiO2 masking (GCA Calibration pattern) [2]
1/12/22 DJ_InP#3 4.5 x 3 13.5 612 71nm left ~50% SiO2 masking (GCA Calibration pattern) [3]
1/26/22 NP_? 10 x 10 100 400-450 ~250nm left ~30-40% SiO2 masking (NingC's pattern)
1/26/22 NP_? 1/4 of 50mm wafer 490 378 276nm left ~30-40% SiO2 masking (NingC's pattern) [1]
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